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高温养护条件下环氧树脂基砂浆早期性能研究
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TU57+8.11

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国家自然科学基金面上项目(52278287)


Research on Performance at Early Stage for Epoxy Resin Based Mortar under Curing Conditions at High Temperature
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    摘要:

    环氧树脂材料具有一定的温度敏感性,因此探究养护温度对环氧树脂基砂浆性能的影响特点十分必要。为进一步明晰高温(30~60 ℃)养护条件下环氧树脂基砂浆早期物理力学特性的演变规律,对其凝结时间、抗折强度及抗压强度进行了测试,并结合扫描电镜(SEM)及压汞(MIP)技术,分析了环氧树脂基砂浆的微观结构特征。试验结果表明:随着养护温度的升高,环氧树脂基砂浆的凝结时间逐渐缩短,并且凝结时间与养护温度之间大致呈现出线性递减的演变关系。在高温养护条件下,随着温度的升高,环氧树脂基砂浆的早龄期(4 h~3 d)抗折强度及抗压强度均先缓慢增大,再急剧下降。当养护温度为40 ℃时,环氧树脂基砂浆的强度特性相对最佳,4 h龄期试件的抗折、抗压强度分别达到21.4 MPa和56.8 MPa。在40 ℃的养护条件下,环氧树脂基砂浆的固化反应较为完全,基体内部结构均匀密实,无明显的孔洞、裂隙等缺陷,而在60 ℃的养护条件下,环氧树脂基砂浆的固化反应不够充分,基体内部结构松散杂乱,原始缺陷增多。

    Abstract:

    Epoxy resin is sensitive to temperature, so it is necessary to explore the influence of curing temperature on the performance of epoxy resin based mortar. In order to further clarify the evolution law of early physical and mechanical properties of epoxy resin based mortar under curing conditions of different high temperature (30~60 ℃), its setting time, flexural strength, and compressive strength are tested. And the microstructure characteristics of epoxy resin based mortar are analyzed in combination with scanning electron microscopy (SEM) and mercury intrusion porosimetry (MIP). The experimental results show that with the increment of curing temperature, the setting time of epoxy resin based mortar shortensgradually, and there is a roughly linear decreasing relationship between the setting time and the curing temperature. Under curing conditions of high temperature, with the increment of temperature, the flexural strength and compressive strength of epoxy resin mortar at an early age (4 h~3 d) first slowly increase, and then sharply decrease. When the curing temperature is at 40 ℃, the strength characteristics of epoxy resin based mortar are relatively optimal, and the flexural strength and compressive strength of the specimens cured for 4 h reach 21.4 MPa and 56.8 MPa respectively. Under the curing conditions of 40 ℃, the curing reaction of epoxy resin based mortar is complete relatively, and the internal structure of the matrix is uniform and dense, without obvious micro defects such as pores and cracks. However, under the curing conditions of 60 ℃, the curing reaction of epoxy resin based mortar is not sufficient, and the internal structure of the matrix is loose relatively and disordered with a significant increment of micro defects.

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夏伟, 白二雷, 吕炎, 许金余, 秦立军.高温养护条件下环氧树脂基砂浆早期性能研究[J].空军工程大学学报,2024,25(6):113-118

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  • 在线发布日期: 2024-12-06
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